Naturally occurring organic acids for organocatalytic synthesis of pyrroles via Paal–Knorr reaction

Research on Chemical Intermediates - In this study, common naturally occurring organic acids, namely oxalic, malonic, succinic, tartaric and citric acid (as safe, inexpensive, and biodegradable...     

Antibacterial and antioxidant properties of phyto-synthesized silver nanoparticles using Lavandula stoechas extract

Due to environmentally friendly and cost- effective issues, biological methods for silver nanoparticles (AgNPs) synthesis are advantageous over chemical and physical ones. In this study, AgNPs synthesized using Lavandula stoechas extract as a reductant and its antioxidant capacity, antibacterial property and cytotoxicity effect were investigated. The phyto-synthesized AgNPs were characterized using various analyses such as transmission electron microscopy (TEM), scanning electron microscopy (SEM), x-ray diffraction (XRD) as well as Fourier transform infrared (FT-IR). The prepared nanoparticles were spherical on shape with the size about 20–50 nm. Antibacterial studies through agar disk diffusion method confirmed the antibacterial potential of phyto-synthesized AgNPs toward two clinical Staphylococus aureus and Pseudomonas aeruginosa bacteria, although MTT assay demonstrated that S. aureus (MIC = 125 μg/ml) was more susceptible to AgNPs than P. aeruginosa (MIC = 250 μg/ml). Moreover, the cytotoxicity assay of phyto-synthezied AgNPs showed a low cytotoxic effect on RAW264 cell line at 62.5 μg/ml as an effective concentration. Also the considerable antioxidant capacity of the AgNPs confirmed through DPPH assay. Great antibacterial and antioxidant properties along with biocompatibility make the suggested phyto-synthesized AgNPs a great candidate for different biomedical applications including wound healing.     

Optimization by Response Surface Methodology of the Adsorption of Anionic Dye on Superparamagnetic Clay/Maghemite Nanocomposite

Russian Journal of Applied Chemistry - Magnetic nanoparticles and clay minerals combine to form a class of advanced nanocomposites that would possess exceptional adsorption, magnetism, and...     

Using multi-criteria decision-making methods to select the best location for the construction of a biomass power plant in Iran

Journal of Thermal Analysis and Calorimetry - Biomass is one of the most convenient types of renewable energy resources around the world. Densely populated areas all over the globe produce a vast...     

Bridge effect on the charge transfer and optoelectronic properties of triphenylamine-based organic dye sensitized solar cells: theoretical approach

Research on Chemical Intermediates - In this work, a series of six organic dyes-sensitized solar cells (DSSCs) combining various π-bridges with a fixed donor (triphenylamine) and a fixed...     

Quasi‐polynomial mixing of critical two‐dimensional random cluster models

We study the Glauber dynamics for the random cluster (FK) model on the torus with parameters (p,q), for q ∈ (1,4] and p the critical point p_c. The dynamics is believed to undergo a critical slowdown, with its continuous‐time mixing time transitioning from for p ≠ p_c to a power‐law in n at p = p_c. This was verified at p ≠ p_c by Blanca and Sinclair, whereas at the critical p = p_c, with the exception of the special integer points q = 2,3,4 (where the model corresponds to the Ising/Potts models) the best‐known upper bound on mixing was exponential in n. Here we prove an upper bound of at p = p_c for all q ∈ (1,4], where a key ingredient is bounding the number of nested long‐range crossings at criticality.     

Design of organic superacids based on triflic and perchloric acid by using DFT-B3LYP calculations

Structural Chemistry - Comprehensive density functional theory calculations at B3LYP/6-311++G(d, p) level have been undertaken on a new type of organic Brønsted acids based on perchloric and...     

Dynamic behavior investigation of capillary rising at various dominant forces using free energy lattice Boltzmann method

Meccanica - A Free Energy Lattice Boltzmann Method has been developed to characterize dominant forces and regimes involved in the capillary rise imbibition process. The comparison of the capillary...     

Step-by-step synthesis of copper(I) complex supported on platinum nanoparticle-decorated mesoporous silica hollow spheres and its remarkable catalytic performance in Sonogashira coupling reaction

In this study, a step-by-step method for the synthesis of platinum nanoparticles and copper(I) complex supported on mesoporous silica hollow spheres (Pt-MSHSs-Cu) is introduced. Scanning electron microscopy, transmission electron microscopy, powder X-ray diffraction, Fourier transform infrared spectroscopy, nitrogen adsorption–desorption, energy-dispersive X-ray spectrometry, X-ray photoelectron spectroscopy, and elemental and thermogravimetric analyses were applied for characterization of the surface, structure, size, phase composition, and morphology of the synthesized materials. The characterized material, Pt-MSHSs-Cu, was used as an efficient and heterogeneous catalyst in the Sonogashira coupling reaction under different reaction conditions. In comparison with MSHSs, Cu(I)-functionalized MSHSs (MSHSs-Cu), and Pt-MSHSs samples, the Pt-MSHSs-Cu catalyst exhibited significantly increased catalytic performance with 91.50% yield. Therefore, the results obtained suggested a synergistic effect derived from platinum nanoparticles, MSHSs substrate, and copper(I) complex, which enhanced the rate of the Sonogashira coupling reaction.     

Functionalization of 1,2,3-Triazole to Pyrimidine,Pyridine, Pyrazole,and Isoxazole Fluorophores with Antimicrobial Activity

Russian Journal of General Chemistry - The multi-component reaction of diacetyl triazole derivative with ethyl cyanoacetate and various aromatic aldehydes according to the conventional and solvent...